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Updated: Jul 26, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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使用适应性动态同质催化反应的一般交叉合反应

Indrajit Ghosh1, Nikita Shlapakov2,3, Tobias A Karl2

  • 1Fakultät für Chemie und Pharmazie, Universität Regensburg, Regensburg, Germany. Indrajit1.Ghosh@chemie.uni-regensburg.de.

Nature
|June 14, 2023
PubMed
概括

这项研究引入了适应性动态同质催化 (AD-HoC) 使用用于多功能C(sp2) 异构原子交叉合反应. 这种自我调整系统简化了多种核友和键形成的反应优化.

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
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