氧化碳化涂层由定义的自下而上的纳米结构组成
Georg Robert Johannes Artus1, Davide Bottone1, Stefan Seeger1
1Department of Chemistry, University of Zurich, Winterthurerstrasse 190, Zurich, CH-8057, Switzerland.
Small (Weinheim an der Bergstrasse, Germany)
|June 15, 2023
概括
研究人员开发了一种新方法来制造高表面积的氧化碳 (SiOC) 涂层. 这些有纹理的SiOC材料具有出色的热稳定性,显示了催化和储能应用的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 陶和玻璃制品以及玻璃制品.
背景情况:
- 氧化碳 (SiOC) 材料是先进的玻璃和玻璃陶,具有理想的化学和热性能.
- 高表面积和热稳定性对于催化,传感和离子存储等应用至关重要.
研究的目的:
- 报告一种简单的自下而上的方法来合成纹理,高表面积的SiOC涂层.
- 为了研究在高温下化SiOC结构的热行为和稳定性.
主要方法:
- 精确定义的聚氧结构 (纳米纤维,微棒) 的直接 Pyrolysis.
- 使用富里埃变换红外光谱学 (FT-IR),扫描电子显微镜 (SEM) 和能量分散式X射线光谱学 (EDX) 进行高达1400°C的热分析.
主要成果:
- 微杆结构保持了它们的面积比,体积缩小约30%至1100°C.
- 纳米尺寸的纤维在900°C时表现出粘性流,这可能是由于纳米尺寸的影响.
- 在氧化玻璃中研究尺寸效应对玻璃过渡温度的潜在潜力.
结论:
- 开发的方法产生了具有显著热稳定的高表面积SiOC涂层.
- 在高温催化,二氧化碳转化和离子储存材料中的应用中,SiOC结构显示出前景.
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