碳酸吸附剂在沉积物中隔离老化有机污染物的有效性有限
Allison R Taylor1, Jie Wang1,2, Parminder Kaur1
1Department of Environmental Sciences, University of California, Riverside, California 92521, United States.
Environmental science & technology
|June 15, 2023
概括
沉积物中的疏水性有机污染物 (HOC) 的老化减少了它们的可用性. 碳酸吸附剂在减少老年海洋沉积物中的DDT生物积累方面表现出有限的有效性,这表明老化对整治策略至关重要.
科学领域:
- 环境科学 环境科学
- 环境化学环境化学
- 生态毒理学 生态毒理学
背景情况:
- 在老化沉积物中的疏水性有机污染物 (HOC) 由于生物可用性降低,造成修复挑战.
- 碳酸吸附剂被提议用于高氧化物修复,但它们的有效性可能受到污染物的老化限制.
研究的目的:
- 评估碳酸吸附剂 (生物炭,粉状活性炭,颗粒状活性炭) 在减少老年海洋沉积物中DDT生物积累方面的有效性.
- 评估污染物衰老对剂基整治性能的影响.
主要方法:
- 污染DDT残留的老海洋沉积物被修改为三种类型的碳酸吸附剂.
- 沉积物在海水中化长达1年的时间.
- 测量了多基Neanthes arenaceodentata的自由溶解的DDT度 (Cfree) 和生物沉积堆积因子 (BSAF).
主要成果:
- 尽管DDT的散装度很高,但自由溶解度和BSAF非常低,表明生物可用性有限.
- 添加碳酸吸附剂并没有持续减少DDT的生物积累.
- 吸附剂的有限有效性归因于DDT在沉积物中的长期老化.
结论:
- 污染物老化显著降低了沉积物中高氧化碳的可用性.
- 碳酸吸附剂在修复老化HOC污染方面可能具有有限的有效性.
- 修复策略必须考虑污染物的老化过程,以成功恢复现场.
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