结合一种正电荷纳米过膜的本质胺,具有较高的选择性和对双价离子的排斥
Zhe Wang1, Jiawei Cao1, Fan Zhang1
1Joint Research Center for Protective Infrastructure Technology and Environmental Green Bioprocess, School of Environmental and Municipal Engineering, Tianjin Chengjian University, Tianjin 300384, China
概括
一种新的正电荷纳米过 (NF) 膜是使用界面聚合来开发的. 这种新的膜显示出对双价离子的优良选择性和改善的抗物性质.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 带正电荷的纳米过 (NF) 膜在从水溶液中分离双价离子时表现出卓越的性能.
- 界面聚合 (IP) 是制造薄膜复合膜的一个关键技术.
研究的目的:
- 开发一种新的,高效的,准确的正电荷NF膜.
- 为了研究合并的phthalimide对膜性能和稳定性的影响.
主要方法:
- 通过聚乙烯胺 (PEI) 和聚胺在聚硫 (PSF) 基板上的界面聚合 (IP) 制造NF活性层.
- 优化NF膜制造条件的优化.
- 使用牛血清白蛋白 (BSA) 评估纯水流量,盐排斥和防性质.
主要成果:
- 在0.4 MPa时,实现了7.09 L·m-2·h-1的纯水流量.
- 对于无机盐具有很好的选择性,其排斥顺序为MgCl2 > CaCl2 > MgSO4 > Na2 SO4 > NaCl.
- 在用BSA过6小时后,获得了1000mg/LMgCl2的94.33%排斥率和81.64%的流量回收比率 (FRR).
结论:
- 开发的NF膜提供了一种高效且简单的定制方法.
- 结合甲胺增强了膜的稳定性和排斥性能.
- 新的膜显示了水处理应用的巨大潜力,特别是对双价阳离子去除和防抗性的潜力.
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