巨大的负热膨胀在一个[8]uril-enabled uranyl-organic polythreading框架通过热诱导放松
Qiu-Yan Jin1,2, Yuan-Yuan Liang1,2, Zhi-Hui Zhang3
1Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences Beijing 100049 China meil@ihep.ac.cn shiwq@ihep.ac.cn.
Chemical science
|June 16, 2023
概括
研究人员开发了一种灵活的基-有机框架,U3(bcbpy) 3(CB8),表现出显著的负热膨胀 (NTE). 这种新型材料显示出独特的时间依赖的动态,由于热诱导的放松,为功能性材料提供了新的途径.
科学领域:
- 材料科学 材料科学 材料科学
- 超分子化学 超分子化学
- 纳米技术 纳米技术
背景情况:
- 有效调节材料热膨胀是一个关键的挑战.
- 金属有机框架 (MOFs) 通过链模型表现出负热膨胀 (NTE).
- 在传统的MOF结构之外探索新的NTE机制是必不可少的.
研究的目的:
- 为可调节的热膨胀开发一个新的框架,包括宿主-客客复合.
- 为了研究柔性黄[8]uril uranyl-有机聚线框架的NTE特性和机制,U3(bcbpy) 3(CB8).
- 探索超分子复合体在设计高级功能材料中的潜力.
主要方法:
- 使用主机-客户端复杂化构建一个多线程框架 U3(bcbpy) 3(CB8).
- 温度依赖的晶体分析以捕捉结构动态.
- 热膨胀系数的表征和NTE机制的识别.
主要成果:
- U3(bcbpy) 3(CB8) 呈现出显著的负热膨胀 (NTE),体积系数为 -962.9 × 10^-6 K^-1 在 260 K 和 300 K 之间.
- NTE归因于一种新的热诱导放松过程,涉及伪托拉单元的弹式收缩,与MOF轮不同.
- 该框架表现出独特的依赖时间的结构动态,这是NTE材料的首次,因为其结构灵活性和粘合力较弱.
结论:
- 该研究提出了一个可行的途径,用于探索新的NTE机制,使用量身定制的超分子宿主-客体综合体.
- U3 ((bcbpy) 3 ((CB8) 框架表现出高度的结构灵活性和适应性,导致可控制的热响应行为.
- 这项工作对设计具有可调节的热性质的高级功能金属有机材料充满希望.
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