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相关概念视频

Acid-Catalyzed Hydration of Alkenes02:45

Acid-Catalyzed Hydration of Alkenes

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Alkenes react with water in the presence of an acid to form an alcohol. In the absence of acid, hydration of alkenes does not occur at a significant rate, and the acid is not consumed in the reaction. Therefore, alkene hydration is an acid-catalyzed reaction.
14.4K
Aldehydes and Ketones with Water: Hydrate Formation01:20

Aldehydes and Ketones with Water: Hydrate Formation

3.3K
An oxygen-based nucleophile, like water, can undergo addition reactions with aldehydes and ketones. The reaction leads to the formation of hydrates, also referred to as 1,1-diols or geminal diols.
The formation of hydrates is a reversible reaction. Hydrate formation is influenced by steric and electronic factors accompanying the alkyl substituents on the carbonyl group: The rate of hydrate formation increases with a decrease in the number of alkyl groups attached to the carbonyl carbon. Hence,...
3.3K
Preparation of Alcohols via Addition Reactions02:15

Preparation of Alcohols via Addition Reactions

6.3K
Overview
The acid-catalyzed addition of water to the double bond of alkenes is a large-scale industrial method used to synthesize low-molecular-weight alcohols. An acidic atmosphere is required to allow the hydrogen in the water molecule to act as an electrophile and attack the double bond in an alkene. The addition of a proton to the double bond creates a carbocation intermediate. The proton preferentially bonds to the less substituted end of the double bond to create a more stable carbocation...
6.3K
Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

12.2K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
12.2K
Leveling Effect01:29

Leveling Effect

841
In acid-base chemistry, the leveling effect refers to the limitation imposed by the solvent on the strength of acids and bases in solution. When a base stronger than the solvent's conjugate base is used, it deprotonates the solvent until the base is entirely consumed, making it ineffective against weaker acids. Conversely, an acid stronger than the solvent's conjugate acid protonates the solvent until the acid is depleted, rendering it ineffective against weaker bases. Essentially, the...
841
Esters to Carboxylic Acids: Acid-Catalyzed Hydrolysis01:13

Esters to Carboxylic Acids: Acid-Catalyzed Hydrolysis

3.0K
Hydrolysis of esters under acidic conditions proceeds through a nucleophilic acyl substitution. In the presence of excess water, the reaction proceeds in a reversible manner, forming carboxylic acids and alcohols.
During hydrolysis, the ester is first activated towards nucleophilic attack through the protonation of the carboxyl oxygen atom by the acid catalyst. The protonation makes the ester carbonyl carbon more electrophilic. In the next step, water acts as a nucleophile and adds to the...
3.0K

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A Simple, Low-cost, and Robust System to Measure the Volume of Hydrogen Evolved by Chemical Reactions with Aqueous Solutions
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通过水结构操纵促进性气进化反应.

Yan Jiao1, Yao Zheng1

  • 1School of Chemical Engineering, The University of Adelaide, North Terrace, SA-5005, Australia.

Angewandte Chemie (International ed. in English)
|June 17, 2023
PubMed
概括

研究人员通过操纵电极-电解质接口的电场对水结构进行改进,改进了性进化反应 (HER). 这一突破,使用IrRu单原子位点,加速水解离,提高HER效率.

科学领域:

  • 电化学 电化学 电化学
  • 材料科学 材料科学 材料科学
  • 表面科学是一门学科.

背景情况:

  • 对于性演化反应 (HER) 的传统电催化剂设计侧重于中间吸附.
  • 最近的进步探索水界结构操纵,以提高HER的性能.

研究的目的:

  • 研究原子局部电场对性HER的界面水结构的影响.
  • 开发新的电催化剂设计,以增强水分离和进化.

主要方法:

  • 利用IrRu的双胞胎单原子位点来创建局部电场.
  • 采用先进的建模,表征技术和电化学测量.
  • 检查了水分子与电极-电解质接口上的催化剂表面之间的相互作用.

主要成果:

  • 证明局部电场显著加速水分离.
  • 通过使用新的单原子站点设计,在性HER性能上取得了显著的改善.
  • 提供了对水-催化剂相互作用及其对动力学影响的详细见解.

结论:

  • 通过局部电场操纵界面水结构是促进性HER的有希望的策略.
  • 双胞胎单原子站点为设计高效电催化剂提供了一个新的平台.
关键词:
酸演化反应的反应接口水结构 接口水结构当地电场 当地电场单原子站点是一个单原子站点.水分离的方法是:水分离.

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  • 这项研究加深了对电催化中的水解离机制的理解.