通过Fe0/PS系统与 Askorbic 酸和磁化前的双重促进的西普洛素降解
Chenkai Hu1, Minjie Chen1, Lei Wang1
1College of Civil Engineering, Zhejiang University of Technology, Hangzhou, 310023, China.
Chemosphere
|June 18, 2023
概括
这项研究引入了一种使用预磁化零价值铁 (Fe0) 与酸 (AA) 和酸盐 (PS) 的新方法,以有效地降解水中的酸. 优化的系统几乎完全消除了CIP,为制药污染提供了有前途的解决方案.
科学领域:
- 环境化学环境化学
- 水处理技术 水处理技术
- 先进的氧化过程 先进的氧化过程
背景情况:
- 持续性制药污染物西普洛素 (CIP) 在水生环境中越来越多地被检测到.
- 传统的零价值铁 (ZVI) 降解耐火污染物的方法在实际应用和持续的催化活性方面面临着挑战.
- 开发有效和稳定的方法来消除CIP对于环境保护至关重要.
研究的目的:
- 通过使用一种新的预磁化Fe0/硫酸 (PS) /酸 (AA) 系统,研究西普洛素 (CIP) 的降解.
- 为了优化反应条件,包括前Fe0和AA的剂量,并评估pH和水矩阵组件的影响.
- 在最佳条件下阐明CIP的降解途径.
主要方法:
- 使用预先磁化的零价值铁 (pre-Fe0) 作为催化剂.
- 使用亚酸 (AA) 来提高Fe2+度和硫酸 (PS) 来产生激素.
- 在不同条件下 (剂量,pH,离子强度,天然有机物质) 调查了5mg/L CIP的降解效率.
- 使用高性能液态染色学 (HPLC) 分析了降解产品.
主要成果:
- 在Fe0/PS/AA之前的系统在40分钟内几乎完全消除了5mg/L的CIP.
- 最佳剂量被确定为0.2 g/L前Fe0和0.05 mM AA.
- 随着pH值的增加,CIP降解效率下降,并且受到特定离子 (Cl-, HCO3-) 和酸的显著影响.
- 基于实验数据和文献,为CIP提出了几条降解途径.
结论:
- 预先磁化Fe0/PS/AA系统对于在水生环境中降解西普洛素非常有效.
- 优化条件和对影响因素的理解是成功应用的关键.
- 这种方法为从水中去除持久性制药污染物提供了一个可行的策略.
更多相关视频
15:03Synthesis of Functionalized Magnetic Nanoparticles, Their Conjugation with the Siderophore Feroxamine and its Evaluation for Bacteria Detection
Published on: June 16, 2020
9.3K
08:13Using Magnetometry to Monitor Cellular Incorporation and Subsequent Biodegradation of Chemically Synthetized Iron Oxide Nanoparticles
Published on: February 27, 2021
4.6K
相关概念视频
Factors Affecting Solubility
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
Formation of Complex Ions
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
EDTA: Auxiliary Complexing Reagents
EDTA titrations are usually carried out in highly basic conditions, where the fully deprotonated form of EDTA, Y4−, actively complexes with the free metal ions in the solution. Several metal ions precipitate as hydrous oxide (hydroxides, oxides, or oxyhydroxides) under these conditions, lowering the concentration of free metal ions in the solution. For this reason, auxiliary complexing agents or ligands such as ammonia, tartrate, citrate, or triethanolamine are used in EDTA titrations to...
Masking and Demasking Agents
EDTA titrations may necessitate masking and demasking agents to temporarily protect a particular metal ion in a mixture from the EDTA reaction. These agents facilitate the sequential analysis of the metal ions by forming stable complexes with some—but not all—metal ions during certain steps.
There are many masking agents, such as cyanide, fluoride, triethanolamine, thiourea, and 2,3-bis(sulfanyl)propan-1-ol (formerly 2,3-dimercapto-1-propanol), with the masking agent chosen based on the metal...
There are many masking agents, such as cyanide, fluoride, triethanolamine, thiourea, and 2,3-bis(sulfanyl)propan-1-ol (formerly 2,3-dimercapto-1-propanol), with the masking agent chosen based on the metal...
Colloidal precipitates
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
Extraction: Advanced Methods
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is formed in...
