过程变量及其优化对于甲氧化合 (OCM) 的重要性
Sultan Alturkistani1,2, Haoyi Wang1,2, Ribhu Gautam1
1Physical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), CCRC, Thuwal, Jeddah 23955-6900, Saudi Arabia.
ACS omega
|June 19, 2023
概括
优化甲氧化合 (OCM) 条件,特别是温度和甲/氧比,可以提高C2的选择性和转化. 这项研究提供了一种数据驱动的方法,以最大限度地从天然气中生产乙和乙烯.
科学领域:
- 催化剂是一种催化剂.
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- 甲的氧化合 (OCM) 将天然气转化为有价值的C2化学物质.
- 商业化需要在高甲转化时提高C2选择性.
- 仅仅是催化剂的开发是不够的;过程条件的优化是至关重要的.
研究的目的:
- 优化工艺条件,以最大限度地提高OCM中的C2 (乙和乙烯) 产量.
- 为了研究温度,CH4/O2比率,压力和催化剂负载对OCM性能的影响.
- 开发用于OCM流程优化的预测模型.
主要方法:
- 使用高通量选 (HTS) 进行La2O3/CeO2催化剂.
- 实验的应用统计设计 (DoE) 分析参数数据.
- 使用生产率分析来了解反应机制.
主要成果:
- 建立了与OCM输出响应的过程变量相关的二次方程.
- 确定了CH4/O2比率和温度作为工艺控制的关键参数.
- 在最佳条件下 (800°C,CH4/O2=7,1bar) 实现了61%的C2选择性和18%的甲转化.
结论:
- 过程条件优化显著提高了OCM性能.
- 能源部在操纵OCM产品分销方面提供了灵活性.
- 最佳条件可以提高C2的选择性,同时最大限度地减少COx副产品.
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