低维的高氧化物 (FeCoCrMnNi) 3O4用于超级电容器应用
Yi Yin1, Wei-Bin Zhang1, Xian-Li Zhang1
1College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China. zhangweibin17@cdut.edu.cn.
Dalton transactions (Cambridge, England : 2003)
|June 19, 2023
概括
高氧化物显示出超级电容器的前景. 研究人员通过优化烧温度来提高它们的能量密度,达到332.2 F g-1的特定电容和103.8 W h kg-1.8的能量密度.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 高氧化物 (HEO) 被探索为超级电容器的电极材料.
- 一个关键的挑战是它们有限的能量密度.
研究的目的:
- 提高高温电站的能量密度和特定电容.
- 为了研究烧温度对HEO特性和性能的影响.
主要方法:
- 使用sol-gel方法与过渡金属 (Fe,Co,Cr,Mn,Ni) 合成的HEOs.
- 多种各样的化温度来控制结构形态和结晶性.
- 在1M KOH电解质中使用循环电压计和静电电荷放电来评估电化学性能.
主要成果:
- 在450°C时获得了具有较高表面积 (63.1 m2 g-1) 的螺旋相 (FeCoCrMnNi) 3O4.
- 在一个广的电位窗口 (-1,0.6 V) 中,在0.3 A g-1下达到332.2 F g-1的特定电容.
- 达到 103.8 W h kg-1.1 的改善能量密度.
结论:
- 化温度显著影响HEO微观结构和电化学特性.
- 优化的HEO显示出高性能超级电容器的潜力.
- 设计的微观结构有助于增强储能能力.
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