污泥废水处理过程中溶解有机 (DON) 的演变由FTICR-MS揭示
Ruihong Yin1, Shuyan Zhou2, Dandan Lu1
1School of Environmental and Chemical Engineering, Shanghai Electric Power University, Shanghai 201306, China; College of Environmental Science and Engineering, Institute of Carbon Neutrality, State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China.
The Science of the total environment
|June 19, 2023
概括
这项研究表明,废水处理有效减少溶解有机 (DON) 并在分子水平上改变溶解有机物 (DOM). 先进的处理过程,如化/脱化和超过,显著影响DOM的组成和分子量.
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
- 分析化学 分析化学
背景情况:
- 废水在废水处理中存在挑战,原因是溶解有机物 (DOM) 和溶解有机 (DON) 度高.
- 了解DOM的分子特性对于优化处理过程和控制污染至关重要.
研究的目的:
- 评估多阶段废水处理过程中DOM和DON在分子水平上的去除.
- 调查捷径化/脱化和超过对DOM成分和特性的影响.
主要方法:
- 福利埃变换离子循环子共振质谱法 (FTICR-MS) 用于在分子水平上分析DOM.
- 研究了一种全面的废水处理系统,涉及捷径化/脱化,两级AO和超过.
主要成果:
- 捷径化和脱化显著减少了DON从180 mg/L降至43 mg/L.
- DOM分子量从238Da降至160Da,含化合物 (CHON-DOM) 的增加从65.79%降至72.35%.
- 蛋白DOM下降,而红素DOM和碳水化合物DOM增加,表明转向更芳香和不和的DOM结构.
结论:
- 研究的废水处理过程在去除DON和改变DOM特征方面是有效的.
- 过和化/脱有助于形成更不和,芳香的DOM.
- 这些发现为废水处理中的有针对性的DON控制策略提供了宝贵的见解.
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