在高度紧张的铁弹性LaCoO3薄膜中出现和强大的铁磁绝缘状态
Dong Li1, Hongguang Wang2, Kaifeng Li1
1College of Physics, MIIT Key Laboratory of Aerospace Information Materials and Physics, State Key Laboratory of Mechanics and Control for Aerospace Structures, Nanjing University of Aeronautics and Astronautics, 211106, Nanjing, China.
Nature communications
|June 19, 2023
概括
在LaCoO3膜中的拉伸应变通过创建有序的氧空位和改变离子状态来诱导铁磁. 这一发现为新兴的铁磁绝缘状态提供了洞察力,用于自旋电子应用.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 过渡金属氧化物对旋转电子具有可调节的特性.
- 铁弹性兰他氧化 (LaCoO3) 通常在散装时具有磁性.
- 张力LaCoO3薄膜中意外的铁磁性缺乏明确的机械解释.
研究的目的:
- 为了阐明铁磁性在抗拉拉力LaCoO3薄膜中的起源.
- 调查氧气空缺和结构变化的作用.
- 了解导致铁磁性的电子状态变化.
主要方法:
- 试验性表征应变的LaCoO3薄膜.
- 对氧空位排序和CoO6八面体旋转的分析.
- 密度函数理论 (DFT) 的计算.
主要成果:
- 同时观察有序的氧气空位和抑制的八面体旋转.
- DFT计算显示了修改后的Co 3d-O 2p杂交.
- 削弱了晶体场的分裂,并促进了高离子的高旋转状态.
结论:
- 应变引起的结构和电子变化驱动LaCoO3膜中的铁磁性.
- 从有序的氧空位和高旋转的离子中产生了一个新兴的铁磁绝缘状态.
- 这些发现表明,低功率的自旋电子装置具有潜力.
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