基于纳二胺的随机聚合物,具有轴对称和不对称的电子接受器,用于可控制的形态和增强的填充因子,在全聚合物太阳能电池中
Geunhyung Park1, Yongjoon Cho1,2, Seunglok Lee1
1School of Energy and Chemical Engineering, Perovtronics Research Center, Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST-gil, Ulju-gun, Ulsan 44919, South Korea. yang@unist.ac.kr.
Physical chemistry chemical physics : PCCP
|June 20, 2023
概括
全聚合物太阳能电池 (全PSC) 的分子设计是提高效率的关键. 这项研究表明,轴对称和不对称的电子接受器的布置显著影响这些设备的形态和功率转换效率 (PCE).
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 全聚合物太阳能电池 (全PSC) 提供了热稳定性和机械灵活性等优势.
- 调聚合物组成对于优化功率转换效率 (PCE) 是至关重要的.
研究的目的:
- 研究轴对称和不对称电子受体对全PSC器件的形态和PCE的影响.
- 为改善所有PSC的性能提供对分子设计的见解.
主要方法:
- 合成基于纳二胺 (NDI) 的随机聚物,具有不同的电子受体.
- 使用物理和表面分析对混合物形态的全面调查.
- 结构模拟以了解分子排列效应.
- 所有PSC设备的制造和特征.
主要成果:
- 基于P(NDI-BDD10) 的设备实现了6.80%的高PCE和69.1%的填充因子 (FF).
- 最不对称的P(NDI-TT10) 显示了最低的PCE (4.52%),但增强了FF (65.4%).
- 观察到轴对称和不对称组件对形态和设备性能产生不同的影响.
结论:
- 适当的分子排列对于在所有PSC中实现所需的形态和改善PCE至关重要.
- 轴对称和不对称的电子接受器之间的区别提供了新的分子设计见解.
- 这些发现对于开发高效率的全聚合物太阳能电池具有重要意义.
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