在压力下的结构形成在伸缩导电纳米复合材料的研究
Debmalya Roy1,2, Vaishnav B3, Sarathlal Koyiloth Vayalil3
1DMSRDE, GT Road, Kanpur 208013, India.
The journal of physical chemistry letters
|June 20, 2023
概括
灵活的传感器在拉伸时失去导电性. 这项研究揭示了纳米填充器网络几何学,受到拉伸和回火的影响,决定了用碳黑和聚二甲基氧 (PDMS) 中的碳纳米管制成的导电膜的电稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术 纳米技术
背景情况:
- 灵活的传感器在重复的机械应力后,通常会受到导电能力下降的影响.
- 了解聚合物矩阵内的导电填充剂的结构行为对于提高传感器耐用性至关重要.
研究的目的:
- 在循环拉伸应力下研究聚二甲基 (PDMS) 中导电纳米填充剂 (碳黑和碳纳米管) 的结构演变.
- 阐明纳米填充器网络形成,界面相互作用和灵活导电膜的电特性之间的关系.
主要方法:
- 将碳黑和碳纳米管纳入PDMS,超过透值.
- 对纳米复合材料薄膜的循环拉伸应力和回火的应用.
- 同时在位拉伸,对导电测量和基于同步子的超小角度X射线散射 (USAXS) 实验.
- 碳纳米管表面化学的系统变化,以探测界面相互作用.
主要成果:
- 循环应力和回火导致纳米填充器网络几何学的不可逆转变化.
- 纳米填充剂的碎形尺寸对于分子级相互作用和网络稳定性至关重要.
- 观察到的结构重组与柔性薄膜的电导率和稳定性直接相关.
结论:
- 柔性导电薄膜的长期电性能是由在机械和热刺激下纳米填充器网络结构的不可逆转形成所决定的.
- 定制纳米填充物几何和接口特性是提高灵活传感器导电性和耐用性的关键.
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