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相关概念视频

Structures of Solids02:22

Structures of Solids

14.3K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
14.3K
Surface Tension of Fluid01:22

Surface Tension of Fluid

346
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies...
346
Cohesion01:07

Cohesion

54.4K
Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a...
54.4K
Capillarity in Fluid01:19

Capillarity in Fluid

273
Capillarity describes the movement of liquid in small spaces without external forces acting on it. The capillarity is driven by surface tension and adhesive interactions between the liquid and surrounding solid surfaces. This effect is often seen in narrow tubes, porous materials, and fine particles.
Surface tension is crucial to capillarity. It results from cohesive forces between liquid molecules at the liquid-air boundary, forming a skin that resists external forces. When the capillary tube...
273
Intermolecular Forces and Physical Properties02:56

Intermolecular Forces and Physical Properties

20.9K
20.9K
First Law: Particles in Two-dimensional Equilibrium01:18

First Law: Particles in Two-dimensional Equilibrium

5.1K
Recall that a particle in equilibrium is one for which the external forces are balanced. Static equilibrium involves objects at rest, and dynamic equilibrium involves objects in motion without acceleration; but it is important to remember that these conditions are relative. For instance, an object may be at rest when viewed from one frame of reference, but that same object would appear to be in motion when viewed by someone moving at a constant velocity.
Newton's first law tells us about...
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相关实验视频

Updated: Jul 26, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
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An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids

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在密集液体中出现的结构相关性.

Ilian Pihlajamaa1, Corentin C L Laudicina1, Chengjie Luo1,2

  • 1Soft Matter & Biological Physics, Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600MB Eindhoven, The Netherlands.

PNAS nexus
|June 21, 2023
PubMed
概括

超冷却液体显著改变了它们的四体结构,揭示了复杂的多体相关性,超出了简单的两体相互作用. 了解这些高阶相关性对于准确描述液体行为至关重要.

科学领域:

  • 统计物理 统计物理
  • 凝聚物质物理学 凝聚物质物理学
  • 计算化学计算化学

背景情况:

  • 描述密度和超冷液体的结构是统计物理学的一个基本挑战.
  • 现有的研究主要研究两体结构相关性,对三体相关性的探索有限.

研究的目的:

  • 在密集和超冷液体中量化研究多体静态结构因子.
  • 扩展结构分析超越两体和三体相关性,直到六体水平.

主要方法:

  • 使用分子动力学模拟提取多体静态结构因子.
  • 用密度函数理论推导高达六体水平的结构因子的准确近似值.

主要成果:

  • 超冷却显然增加了四体相关性,类似于下级相关性.
  • 在超冷却时,在小波数下观察到液体四点结构的显著质量和数量变化.
  • 高阶相关性中的这些变化并没有反映在两点结构相关性中.

结论:

  • 超出二粒子层次的多体相关性对于完全了解密集液体结构和动态至关重要.
  • 观察到的四点结构变化凸显了仅依赖于对互动的理论的局限性.
关键词:
合形硬球体是什么意思计算机模拟的计算机模拟.密集的液体 密集的液体密度函数理论密度函数理论结构性相关性 结构性相关性

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  • 未来的液体结构和动态理论必须结合这些高阶相关性来捕捉复杂的液体行为.