- 化电催化电极向葡萄糖氧化合与性气生产
Xinxuan Lin1, Hui Zhong1, Wei Hu1
1Key Laboratory of Advanced Catalysis of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China.
Inorganic chemistry
|June 22, 2023
概括
开发用于葡萄糖氧化反应 (GOR) 的先进电催化剂至关重要. 一种新的NiCoSe纳米板催化剂在两电极电池中显示出高活性和高效的GOR和双功能电催化.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- 电化学葡萄糖氧化反应 (GOR) 为水氧化提供了一个低潜在的替代方案.
- 为GOR开发高效和成本效益的电催化剂仍然是一个挑战.
- 葡萄糖是一种来自生物质的丰富资源.
研究的目的:
- 为GOR开发一种高活性,低成本的电催化剂.
- 在GOR催化过程中调查活性物种和表面演变.
- 为了证明催化剂在双电极电池中的双功能应用,用于配对反应.
主要方法:
- 在Ni泡上支持的NiCoSe纳米板的合成.
- 对GOR的催化剂的电化学表征.
- 在现场进行拉曼光谱,研究表面成分的演变.
- 组装和测试用于配对GOR和进化反应的双电极电池.
主要成果:
- NiCoSe纳米板催化剂在GOR的1.41V与RHE时实现了500mAcm-2的高电流密度.
- 在1.40V与RHE相比,在formate中获得了70.2%的法拉第效率.
- 在现场拉曼光谱学确定了CoOx/CoOOH和NiOOH作为活性物种.
- 双电极电池中的双功能催化剂在1.50V下运行,以达到200mA cm−2为配对反应,稳定性>18h,H2法拉第效率接近100%.
结论:
- 在Ni泡上支的NiCoSe纳米板是GOR的高度活性和稳定的电催化剂.
- 这种催化剂在生物质转化和能源储存方面的应用潜力显著.
- 鉴定的活性物种为设计未来的GOR电催化剂提供了洞察力.
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