基于三元氨基的新型深度环氧溶剂用于二氧化碳捕获的实验研究
Hossam K Abdrabou1,2, Inas AlNashef1,2, Mohammad Abu Zahra1,2
1Department of Chemical Engineering, Khalifa University, Abu Dhabi, United Arab Emirates.
PloS one
|June 23, 2023
概括
将水添加到三元氨基基的深溶解剂 (DES) 中,可显著降低粘度高达25%,同时保持高的二氧化碳吸收能力. 这些稳定的DES对碳捕获应用具有前景.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- 深度环氧溶剂 (DES) 正在成为传统溶剂的有希望的替代品,用于捕获二氧化碳.
- 基于三级氨基的DES具有高的二氧化碳吸收能力,但往往具有高粘度,阻碍了它们的实际应用.
- 在这些系统中,水作为降粘性剂的作用需要进一步研究.
研究的目的:
- 研究添加水对三元胺基DESs物理化学性质,热稳定性和二氧化碳吸收的影响.
- 探索水含量,键接受器 (HBA),键供体 (HBD) 和HBA:HBD比对DES性能的影响.
- 使用COSMO-RS模型预测二氧化碳吸收能力,并与实验数据进行比较.
主要方法:
- 制备和表征三元氨基基基DESs的含水量变化.
- 测量粘度,热稳定性和二氧化碳吸收能力.
- 使用COSMO-RS模型预测二氧化碳的溶解度和评估影响因素.
主要成果:
- 含有5-10%重量的水,在室温下将DES粘度降低高达25%.
- 高二氧化碳吸收能力 (0.155-0.170 g CO2 / g DES) 在添加水的情况下得到维持.
- 三级DES表现出高达125°C的良好热稳定性.
- 科斯莫-RS准确地预测了二氧化碳溶解度趋势和各种参数的影响.
结论:
- 水是一种有效的添加剂,可以降低三元氨基基基DES的粘度,而不会影响二氧化碳捕获性能.
- 这些水改性DES具有很高的热稳定性,使其适用于燃烧后的二氧化碳捕获.
- 科斯莫-RS是指导设计和优化二氧化碳捕获DES的宝贵工具.
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