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相关概念视频

Bond Energies and Bond Lengths02:49

Bond Energies and Bond Lengths

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Stable molecules exist because covalent bonds hold the atoms together. The strength of a covalent bond is measured by the energy required to break it, that is, the energy necessary to separate the bonded atoms. Separating any pair of bonded atoms requires energy — the stronger a bond, the greater the energy required to break it.
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The bond between aggregate particles and the cement matrix is significantly influenced by the shape and surface texture of the aggregates. High-strength concretes benefit from a rougher texture, which leads to stronger bonding due to greater adhesion. Angular aggregates with larger surface areas also enhance this bond. The bonding quality, however, is complex to assess as no universally accepted test exists. Good bonding is indicated when a crushed concrete specimen shows some aggregate...
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Radical Chain-Growth Polymerization: Chain Branching01:17

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The skeletal structure of polymers synthesized via radical polymerization is always branched. For example, the polymerization of ethylene by radical polymerization results in a low-density grade of polyethylene with a heavily branched skeletal structure. Here, the radical site abstracts hydrogen from the growing chain, and the radical site shifts from the end (a primary carbon center) to anywhere within the growing chain (a secondary carbon center). Consequently, the part of the chain from the...
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Atoms participate in a chemical bond formation to acquire a completed valence-shell electron configuration similar to that of the noble gas nearest to it in atomic number. Ionic, covalent, and metallic bonds are some of the important types of chemical bonds. Bond energy and bond length determine the strength of a chemical bond.
Types of Chemical Bonds
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A peptide bond covalently attaches amino acids through a dehydration reaction. One amino acid's carboxyl group and another amino acid's amino group combine, releasing a water molecule. The resulting bond is the peptide bond. The products that such linkages form are peptides. As more amino acids join this growing chain, the resulting chain is a polypeptide. Each polypeptide has a free amino group at one end. This end has the N-terminal, or the amino-terminal, and the other end has a free...
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如何在链条被压缩的同时延长链条

Liel Sapir1,2, James Brock3, Danyang Chen1,2

  • 1Thomas Lord Department of Mechanical Engineering and Materials Science, Duke University, Durham, North Carolina 27708, United States.

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聚合物链延伸可以令人惊地导致键的压缩,挑战典型的假设. 这发生在聚合物刷和网络中,其中散装压力会影响个体键张力.

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科学领域:

  • 聚合物物理 聚合物物理
  • 材料科学 材料科学 材料科学
  • 计算化学的计算化学

背景情况:

  • 聚合物链延伸通常会因形状限制而导致正链张力.
  • 个体键张力受到链张力和散装压力的影响,而不仅仅是链延伸.
  • 一种非直观的关系存在于链条张力增加而键张力减少的地方.

研究的目的:

  • 调查链延伸过程中聚合物键压缩的反直觉现象.
  • 通过使用计算模拟,在聚合物刷和网络中证明这种效应.
  • 为了阐明驱动这种行为的潜在物理机制.

主要方法:

  • 用分子动力学模拟来建模聚合物系统.
  • 分析的重点是链张力,键张力和散装压力之间的关系.
  • 系统参数包括不同的接种密度和网络变形.

主要成果:

  • 增加聚合物刷接种密度导致垂直链延伸和结合压缩.
  • 聚合物网络的压缩导致了自由方向链的扩展和键盘压缩的增加.
  • 发现压力对键张力的贡献在这些系统中占主导地位.

结论:

  • 该研究表明,聚合物链延伸可以导致结合压缩,这与常见的假设相反.
  • 大量压力在确定个体键张力方面起着至关重要的作用,特别是在封闭的聚合物系统中.
  • 这些发现对设计和理解变形下的聚合物材料有影响.