对Co2Fe0.5Cr0.5Al中诱导格子干扰的缺陷和磁相互作用的新见解
Ravi Kumar Yadav1,2, R Govindaraj1,2, K Vinod1,2
1Materials Science Group, Indira Gandhi Centre for Atomic Research Kalpakkam 603102 Tamilnadu India govind@igcar.gov.in.
RSC advances
|June 26, 2023
概括
这项研究揭示了缺陷如何影响Co2Fe0.5Cr0.5Al中的磁相互作用,使用Mössbauer光谱学. 它发现了网格障碍和磁场之间的联系,这表明了自旋电子应用的最佳化.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 磁力学 磁力学 是一种
背景情况:
- 了解缺陷诱导的磁相互作用对于自旋电子材料至关重要.
- 基于Co2FeAl的Heusler化合物对自旋电子应用具有前景.
研究的目的:
- 为了研究原子级缺陷诱导的磁相互作用在Co2Fe0.5Cr0.5Al.
- 将这些相互作用与Co2Fe0.8Cr0.2Al和Co2FeAl.Al进行比较.
- 建立格子障碍,磁性特性和火处理方法之间的相关性.
主要方法:
- 采用莫斯巴乌尔光谱法研究了Co2Fe0.5Cr0.5Al,Co2Fe0.8Cr0.2Al和Co2FeAl. 这三种光谱.
- 应用非平衡治疗来诱导缺陷.
- 分析的重点是超精细场和格子排序.
主要成果:
- 观察到价值电子度和平均超精度场之间的线性相关性,在Cr.置换时有不同的斜率.
- 与Co2Fe0.8Cr0.2Al.Al.相比,在Co2Fe0.5Cr0.5Al中发现了缺陷度和类型的显著变化.
- 超精细场与格子秩序/混乱程度之间建立了直接的相关性.
结论:
- 缺陷诱导的磁相互作用在基于CO2FeAl的化合物的磁性中起着关键作用.
- 格子障碍显著影响过精细场,有序的场所呈现出更高的值.
- 为 Co2Fe0.5Cr0.5Al 的缺陷恢复提出了最佳的回火条件,从而提高了其旋转潜力.
相关概念视频
Metallic Solids
18.5K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
18.5K
Crystal Field Theory - Octahedral Complexes
26.9K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
26.9K
Lattice Centering and Coordination Number
9.7K
The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
Types of Unit Cells
Imagine taking a large number of identical...
9.7K
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Colors and Magnetism
12.0K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
12.0K
Trends in Lattice Energy: Ion Size and Charge
24.0K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
24.0K


