类型Bi的热电性能OX2 (X = Cl, Br) 的热电性能
Tao Wang1,2,3, Wanghua Hu1,2, Zhefeng Lou2,3
1Department of Physics, Fudan University, Shanghai 200433, China.
Materials (Basel, Switzerland)
|June 28, 2023
概括
研究人员探索了用于热电应用的Bi4O4SeX2陶. 调整静电测量保持了超低的导热率,提高了热电性能,功率值高达0.16.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 热电学是一种热电学.
背景情况:
- 多个离子超网Bi4O4SeCl2由于其超低的导热性,显示出热电应用的潜力.
- 优化热电材料需要平衡电传输和热导率.
研究的目的:
- 为了研究Bi4O4SeX2 (X = Cl, Br) 多晶陶的热电特性.
- 为了探索非静电学调对热电性能的影响.
主要方法:
- 合成Bi4O4SeX2 (X = Cl, Br) 多晶陶的方法.
- 通过调整静电学来调整电子度.
- 测量热电性质,包括电传输和热导率.
主要成果:
- 在所有样本中保持了超低的导热率,在高温下接近Ioffe-Regel极限.
- 通过非静态度调整优化了电气传输特性.
- 在770 K.中,达到了高达0.16的优点 (ZT) 数字.
结论:
- 非静电度调是提高Bi4O4SeX2材料热电性能的一个有效策略.
- 这些材料的超低导热率即使在优化的电特性下也保持不变.
- Bi4O4SeX2陶对未来的热电器件应用有希望.
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