基于不同二醇的聚氨的定制动态粘性弹性
Jiadong Wang1, Min Wang1, Chenxin Xu1
1State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China.
Polymers
|June 28, 2023
概括
研究人员通过调整软段灵活性和链延长器结构来定制聚氨 (PU) 动态粘弹性. 这使得在先进的材料应用中可以精确控制损耗峰值温度.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
背景情况:
- 越来越多的人对定制减噪和轮胎材料的需求.
- 聚氨 (PU) 的可设计分子结构为量身定制的特性提供了潜力.
- 动态粘弹性是聚合物的关键性能参数.
研究的目的:
- 研究定制聚氨动态粘弹性的方法.
- 探索PU中的分子结构和粘弹性特性之间的关系.
- 建立一个精确控制PU材料性能的框架.
主要方法:
- 软段灵活性的系统变化.
- 选择具有多种化学结构的链延长器.
- 对分子结构,微相分离和动态粘弹性 (损失峰值温度,模量) 的分析.
主要成果:
- 调整软段灵活性将损失峰值温度转移到 -50 °C 和 14 °C 之间.
- 更规则的链延长器结构增加了软硬段相互作用和微相分离.
- 修改链延长器分子重量精确控制了从-1°C到13°C的损失峰值温度.
结论:
- 量身定制软段和链延长器特性,可以精确控制PU动态粘性弹性.
- 优化微相分离是实现所需材料性能的关键.
- 这项研究为开发用于特定应用的先进PU材料提供了一种新的方法.
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