优化条件,以获得具有不同废水处理所需的阴离子度的阴离子聚烯胺乳液共聚物,用于不同的废水处理
Tung Huy Nguyen1, Linh Pham Duy Nguyen1, Thao Thi Phuong Nguyen1
1Center for Polymer Composite and Paper, School of Chemical Engineering, Hanoi University of Science and Technology, Hanoi 11600, Vietnam.
Polymers
|June 28, 2023
概括
这项研究使用响应表面方法优化了化聚烯胺 (CPAM) 合成. 这种新方法有效地产生了针对有效的废水处理应用量身定制的阴离子度的CPAM.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
背景情况:
- 性多烯胺 (CPAM) 在废水处理等行业中至关重要.
- 之前的研究重点是分子量和花效应,而不是离子度优化.
- 对于CPAM合成的传统单因素实验是低效和昂贵的.
研究的目的:
- 为了优化CPAM合成参数,以达到所需的阴阳度.
- 克服传统单因素优化方法的局限性.
- 开发一种快速合成CPAMs的模型,其分离度不同.
主要方法:
- 响应表面方法 (RSM) 用于优化.
- 研究的关键参数:单体度,阴离子单体含量和启动剂含量.
- 描述技术包括1H-NMR,FTIR,SEM,BET,DLS和GPC等.
主要成果:
- 成功合成了低 (21.85%),中 (40.25%) 和高 (71.17%) 离子度的CPAM乳液.
- 优化条件为每个所需的阴离子度提供了特定的单体和启动剂度.
- 合成的CPAM在废水处理中表现出有效的性能,符合技术法规.
结论:
- RSM为CPAM合成优化提供了传统方法的高效替代方案.
- 开发的模型允许快速生产针对工业需求的具有特定离子度的CPAM.
- 优化CPAM是废水处理中的有效花剂,符合环境标准.
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