消耗咖啡粉对多乳酸复合材料的结晶性和粘弹性行为的影响
Anne Shayene Campos de Bomfim1, Daniel Magalhães de Oliveira1, Kelly Cristina Coelho de Carvalho Benini1
1Fatigue and Aeronautical Materials Research Group, Department of Materials and Technology, UNESP-São Paulo State University, Guaratinguetá 12516-410, SP, Brazil.
Polymers
|June 28, 2023
概括
本研究探讨使用消耗的咖啡粉 (SCG) 来增强多乳酸 (PLA) 生物复合材料. 20%重量的SCG复合材料提供了平衡的性能,提高了刚性和更低的密度,使其成为包装和3D打印的可持续替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 可持续材料 可持续材料
背景情况:
- 聚乳酸 (PLA) 是一种具有机械性能限制的可生物降解聚合物.
- 消耗的咖啡粉 (SCG) 是一个丰富的废物,具有价值化潜力.
研究的目的:
- 研究将SCG纳入PLA以制造新的生物复合材料的方法.
- 评估SCG含量对PLA机械,物理,热和质性质的影响.
主要方法:
- 使用双螺丝挤出复合PLA和SCG (0-30%重量).
- 生物复合材料是通过压缩成型的.
- 分析了各种性能,包括机械,物理,热和学的特征.
主要成果:
- 由于SCG的异质核化,PLA结晶性显著增加 (34-70%).
- 复合材料表现出较低的玻璃过渡温度 (1-3°C),密度降低,并且随着SCG含量的增加,性降低.
- 更高的SCG含量导致了增强的聚合物链流动性和降低融粘度.
结论:
- 生物复合材料含有20%的SCG显示出最有利的性能平衡,与整洁的PLA相比或优于它.
- 这种SCG-PLA复合材料为包装和3D打印等应用提供了具有成本效益和可持续性的替代方案,需要更低的密度和更高的刚度.
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