在催化界面上高效的O-O合,以协助对水氧化协同和顺序性质子电子转移的动力学优化
Chen Qiao1,2, Zahid Usman3, Jie Wei4
1Research Center of Materials Science, Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications, Beijing Institute of Technology, Beijing 100081, People's Republic of China.
ACS nano
|June 28, 2023
概括
一个新的策略通过控制活性位点中间体来优化催化剂动力学. 硫化Co-NiFe-LDH纳米片促进M-OOH的形成,增强氧演化反应 (OER) 在性介质中的性能.
科学领域:
- 催化剂是一种催化剂.
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
背景情况:
- 优化催化剂动力学对于高效的电化学反应至关重要.
- 控制活性位点中间体的吸附是提高催化性能的关键.
- 了解不同条件下的反应机制对于催化剂设计至关重要.
研究的目的:
- 提出一种基于调整活性位点中间体吸附的催化剂动力学优化策略.
- 在速度决定步骤 (RDS) 之前调查M-OOH中间体的形成.
- 在弱性环境中探索氧进化反应 (OER) 机制.
主要方法:
- 硫化Co-NiFe-LDH纳米片的合成.
- 在现场进行拉曼光谱,以确认中间形成.
- 电荷转移适配分析.
- 电化学测量用于研究OER动力学.
主要成果:
- 显著降低了O-O合的动能屏障.
- 在低超电位下形成M-OOH中间体.
- 在现场通过拉曼和电荷转移配件确认M-OOH形成.
- 在弱性介质中证明了硫化Co-NiFe-LDH的优良OER动力学.
结论:
- 拟议的策略通过管理活性位点中间体,有效地优化催化剂动力学.
- 硫酸-NiFe-LDH由于高效的M-OOH形成,表现出优越的OER性能.
- 该研究提供了对OER机制的见解,特别是在质子转移受限环境中从CPET转向SPET的转变.
相关概念视频
Catalysis
27.1K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
27.1K
Introduction to Mechanisms of Enzyme Catalysis
8.3K
For many years, scientists thought that enzyme-substrate binding took place in a simple "lock-and-key" fashion. This model stated that the enzyme and substrate fit together perfectly in one instantaneous step. However, current research supports a more refined view scientists call induced fit. The induced-fit model expands upon the lock-and-key model by describing a more dynamic interaction between enzyme and substrate. As the enzyme and substrate come together, their interaction causes...
8.3K
Oxidative Cleavage of Alkenes: Ozonolysis
10.6K
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
10.6K
Electron Transport Chains
100.0K
The final stage of cellular respiration is oxidative phosphorylation that consists of two steps: the electron transport chain and chemiosmosis. The electron transport chain is a set of proteins found in the inner mitochondrial membrane in eukaryotic cells. Its primary function is to establish a proton gradient that can be used during chemiosmosis to produce ATP and generate electron carriers, such as NAD+ and FAD, that are used in glycolysis and the citric acid cycle.
The ETC is comprised of...
The ETC is comprised of...
100.0K
Oxygenic Photosynthesis
47
Oxygenic photosynthesis is a fundamental process in which light energy is harnessed to drive the oxidation of water, leading to the production of molecular oxygen (O₂), adenosine triphosphate (ATP), and nicotinamide adenine dinucleotide phosphate (NADPH). This process is essential for sustaining aerobic life on Earth and is primarily carried out by cyanobacteria, algae, and plants. The core of oxygenic photosynthesis lies in the thylakoid membranes, where chlorophyll pigments facilitate...
47
Electron Transport Chain: Complex III and IV
7.7K
During the electron transport chain, electrons from NADH and FADH2 are first transferred to complexes I and II, respectively. These two complexes then transfer the electrons to ubiquinol, which carries them further to complex III. Complex III passes the electrons across the intermembrane space to Cyt c, which carries them further to complex IV. Complex IV donates electrons to oxygen and reduces it to water. As electrons pass through complexes I, III, and IV, the energy released aids the pumping...
7.7K


![Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F55858.jpg&w=3840&q=50)