一项实验和计算调查排除了在二复合体[Cp(CO) 2 Mn(N2 ) 中的N2 连接体上的直接核友性添加

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Updated: Jul 25, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

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Quentin Le Dé1, Amal Bouammali1, Christian Bijani1

  • 1LCC-CNRS, Université de Toulouse, CNRS, UPS, 205 route de Narbonne, BP44099, 31077, Toulouse cedex 4, France.

Angewandte Chemie (International ed. in English)
|June 28, 2023
PubMed
概括

(PhLi) 与二复合物反应时不是在N2联体上,而是在CO联体上,形成一个短暂的乙碳复合物. 这纠正了以前关于二联体活性的发现.

关键词:
一氧化碳的一氧化碳.循环环乙烯基.二氧化二氧化是一种.有机是一种有机.

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