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基于伊米达的甲基化离子液体对粘度的影响:来自补偿阿雷尼乌斯形式主义的新见解

Allison M Fleshman1,2, Allison M Goldman1, Wesley J Hetcher1

  • 1Department of Chemistry, Lawrence University, Appleton, Wisconsin 54911, United States.

The journal of physical chemistry. B
|June 28, 2023
PubMed
概括

意达离子液体的甲基化对粘度的影响不同,取决于离子. 补偿的阿雷尼乌斯形式主义揭示了[Tf2N]-和[B(CN) 4]-离子的不同的激活能量和 entropies.

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