连续共价有机框架膜:从制备策略到应用
Xiaojun Sun1, Mengting Di1, Jie Liu1
1State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, Dalian, 116023, China.
Small (Weinheim an der Bergstrasse, Germany)
|June 29, 2023
概括
共价有机框架 (COF) 为高级分离提供可调节的多孔结构. 本综述详细介绍了COF膜合成和应用,强调了实现无缺陷膜用于气体和水净化的挑战.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 纳米技术纳米技术
背景情况:
- 联有机框架 (COF) 是具有可调节性质的晶体多孔聚合物.
- 它们的常规孔状结构使得它们对基于膜的分离有希望.
- 实现连续,无缺陷的COF膜对于实际应用至关重要.
研究的目的:
- 审查COF中的链接类型,合成和孔径控制.
- 要突出准备连续COF膜的策略.
- 讨论COF膜在各种分离过程中的应用.
主要方法:
- 关于COF合成和膜制造的文献综述.
- 层层堆叠 (LBL) 的分析,现场生长,界面聚合 (IP) 和溶剂造方法.
- 讨论COF膜在气体分离,水处理和储能方面的应用.
主要成果:
- COF 提供多样化的结构和可调节的孔隙,用于分离应用.
- 有各种方法可用于COF膜制备,每个方法都有优点和局限性.
- COF膜在气体分离,水净化和离子导电方面表现出潜力.
结论:
- 连续的,无缺陷的COF膜对于有效的分离至关重要.
- 对于大规模的COF膜生产,需要进一步的研究.
- 导电性COF膜的开发是未来的一个关键方向.
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