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聚甲基Ru (II) 或循环金属化Ir (III) 功能化架构用于光催化
Yan-Lin Li1, Ai-Juan Li1, Sheng-Li Huang1
1MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China. huangsl@bit.edu.cn.
Chemical Society reviews
|June 29, 2023
概括
本综述探讨了MOF和COF等先进架构中的Ru (II) 和Ir (III) 复合体. 这些材料对光催化,包括进化和二氧化碳减排具有前景.
科学领域:
- 协调化学 协调化学
- 材料科学 材料科学 材料科学
- 光催化作用的光催化
背景情况:
- 聚甲基Ru (II) 和循环金属化Ir (III) 复合物具有光活性有利的三重状态.
- 将这些金属超分子单元集成到MOF和COF等框架中,可以扩展网络化学.
- 最近的进展凸显了在各种架构中对Ru (II) 和Ir (III) 金属构造体的兴趣日益增长.
研究的目的:
- 审查Ru(N^N) 3和Ir(C^N) 2(X^N) 功能化架构的设计和合成.
- 探索金属有机框架 (MOF),共价有机框架 (COF) 和各种超分子系统中的应用.
- 提出光催化应用,包括进化和二氧化碳减排.
主要方法:
- 专注于设计和合成策略,以结合Ru (II) 和Ir (III) 复合物.
- 对MOFs,COFs,金属超分子,有机超分子和SOFs等架构的审查.
- 收集各种反应的光催化性能数据.
主要成果:
- 成功地将Ru (II) 和Ir (III) 综合体集成到各种框架架构中.
- 在进化反应 (HER) 中显示了应用潜力.
- 探索二氧化碳还原反应 (CO2RR),光催化氧化和有机转化.
结论:
- Ru (II) 和Ir (III) 复合体是功能架构的多功能构建块.
- 这些金属超分子结构在光催化中提供了令人兴奋的可能性.
- 在这个领域进行进一步的研究有望在可持续化学方面取得重大进展.
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