在对齐的碳纳米管/碳矩阵复合材料中的应力图形化联合理论和实验研究
Liwen Zhang1,2, Małgorzata Kowalik3, Qian Mao3
1Key Laboratory of Multifunctional Nanomaterials and Smart Systems, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, Jiangsu 215123, People's Republic of China.
ACS applied materials & interfaces
|June 29, 2023
概括
复合材料中较高的碳纳米管 (CNT) 含量增强了应力石墨化,改善了机械性能. 这项研究揭示了开发先进CNT/碳矩阵复合材料的原子化机制.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 复合材料 复合材料 复合材料
背景情况:
- 在CNT/碳矩阵 (CNT/C) 复合材料中,碳纳米管 (CNT) -矩阵接口的应力图形化尚未得到充分理解.
- 理论和实验研究之间存在差距,这阻碍了这种现象在高性能复合材料中的应用.
研究的目的:
- 探索基于CNT/聚烯二 (PAN) 的碳基复合材料中应力石墨化的机制.
- 为了研究 CNT 内容和对齐对图形化的影响.
- 为优化 CNT - 矩阵接口提供原子化见解.
主要方法:
- 使用了反应性分子动力学模拟.
- 在基于CNT/PAN的碳矩阵复合膜上进行了实验研究.
- 传输电子显微镜 (TEM) 用于验证.
主要成果:
- 较高的CNT含量导致CNT周围的压力度增加.
- 观察到 PAN矩阵中化基与 CNTs 的对齐.
- 优选脱,碳环聚类和PAN矩阵石墨化发生在1500K.
- 实验验证证证实了在CNTs周围形成额外的石墨层.
- 在拉伸强度 (82%) 和模量 (144%) 中取得了显著的改进.
结论:
- 这项研究阐明了CNT/PAN复合材料中应力石墨化的原子化机制.
- 这些发现为CNT-矩阵接口的预测和可控优化提供了指导.
- 这项研究为开发新型高性能CNT/C复合材料铺平了道路.
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