二烯衍生物:一种用于水性有机流电池的高氧潜能分子
Xianghui Liu1, Tianyu Li1, Changkun Zhang1
1Division of Energy Storage, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
Angewandte Chemie (International ed. in English)
|June 30, 2023
概括
研究人员为水性有机流电池 (AOFB) 开发了新的N替代的西丁类似物. 这些分子具有高氧化还原潜力和出色的可溶性,显著提高了电池性能和能量密度.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 在水性有机流电池 (AOFB) 中提高能量密度需要具有高潜力的水溶性氧化还原活性分子.
- 现有的西丁衍生物在水性应用中面临局限性.
研究的目的:
- 为AOFBs设计N替代的西丁类似物作为水溶性阴解质.
- 为了实现可控制的氧化还原潜力和高溶解度,以提高电池性能.
主要方法:
- 分子工程水性不可逆转的西丁,以创建N替代的类似物.
- 理论计算以将电子结构和性与氧化还原潜力相关联.
- 在AOFB配置中对开发材料进行电化学测试.
主要成果:
- 合成了一系列具有0.78-1.01V与SHE之间的氧化还原潜力的N替代的西丁类似物.
- N,N,N',N'-四乙丁 (TEB) 呈现出高氧化还原潜力 (0.82 V 与 SHE 相比) 和出色的溶解性 (1.1 M).
- 使用TEB作为催解质的AOFB表现出显著的稳定性 (在1200个周期内保持99.4%的容量) 和高库伦比效率 (~100%).
结论:
- 替代N的西丁是高性能AOFB阴解体的有希望的候选物.
- 基于TEB的AOFB实现了41.8Ah L-1的稳定放电能力,具有高库伦比 (97.2%) 和能源 (91.2%) 效率.
- 西丁衍生物的分子设计为推进AOFB技术提供了一个可行的策略.
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