石纤维素固体废物的气压化:低温脱氧和化学结构演变机制
Liu Shi1, Zhenzhong Hu1, Xian Li1
1State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
Bioresource technology
|June 30, 2023
概括
气体压缩化显著增强了基纤维素固体废物的去氧化,高达79%. 这种新的工艺促进了纤维素分解和挥发性物质的转化,与传统方法不同.
科学领域:
- 生物质能源转换生物质能源转换
- 热化学加工的纤维素酸的热化学加工.
背景情况:
- 传统的大气压 (AP) 烧结方法可以实现有限的脱氧 (40%) 基纤维素固体废物 (LSW).
- 在气压 (GP) 烧烤过程中脱氧和结构变化的潜在机制在很大程度上仍未被探索.
研究的目的:
- 为了阐明反应途径和机制,规范LSW脱氧在GP化下.
- 为了比较GP烧烤与AP烧烤对LSW组成和结构的影响.
主要方法:
- 分析GP化过程中的三相产品 (固体,液体,气体).
- 使用指纹分子和碳结构分析,描述化学结构演变的特征.
主要成果:
- 在GP烧烤过程中实现了超过79%的脱氧,远远高于AP烧烤的40%.
- 气压诱导了 >90.4%的纤维素分解和二次聚合,使挥发物质变成固定碳.
- 这些效应在AP烧烤中不存在.
结论:
- 一个脱氧和结构进化机制模型的GP torrefaction被开发出来.
- 这些研究结果为优化GP烧烤工艺提供了理论指导.
- 这项研究有助于了解煤炭和生物质等固体燃料的压力热转换机制.
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