关于毛孔结构和群体演变对浸泡过程中不同大小的煤样本自发燃烧特征的影响的实验研究
1School of Safety and Management Engineering, Hunan Institute of Technology, Hengyang, Hunan 421002, China.
ACS omega
|July 3, 2023
概括
水浸浸改变了煤炭的结构和反应性,减少了自发燃烧的风险. 较小的煤颗粒大小会经历更显著的变化,导致更低的激活能量和更好的安全性.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 煤炭自燃是采矿中的一个重大安全隐患.
- 了解水对煤炭性能的影响对于降低风险至关重要.
研究的目的:
- 研究水浸浸如何影响煤炭孔隙结构,功能组和自燃特性.
- 分析煤炭颗粒大小对这些变化的影响.
主要方法:
- 来自Fengshuigou煤矿的原煤样本被浸泡在水中.
- 使用红外光谱学,燃烧特征分析和氧化反应动力学.
- 量化了孔隙结构,功能组和激活能量的变化.
主要成果:
- 沉浸在水中显著提高了煤炭孔径体积和平均孔径,特别是在较小的颗粒大小中.
- 观察到活性组与氧气之间的接触增加,促进反应性功能组的形成.
- 浸水煤的平均激活能量下降了12.4-19.7%,其中60-120个网格样本的最低值被观察到.
结论:
- 沉浸在水中对煤炭的物理和化学性能产生了积极的改变,可能降低自燃风险.
- 煤炭颗粒的大小是影响水浸效应的关键因素.
- 该研究提供了关于沉浸煤炭自燃机制的见解,有助于安全管理.
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