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Updated: Jul 24, 2025

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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重新思考催化剂捕获在Ni-催化[3,2-b]烯聚合物中的催化剂

Matthew D Hannigan1, Jessica L Tami1, Paul M Zimmerman1

  • 1Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, United States.

Macromolecules
|July 3, 2023
PubMed
概括

由于催化剂的失活,催化剂转移聚合因[3,2-b]二甲而停产. 这项研究揭示了陷是从C-S键插入中产生的Ni(II) 复合体,而不是Ni(0) pi-复合体.

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