电荷捕获和释放到/从深陷中的量子模型
Ivan I Vrubel1, Vasilii Khanin2,3, Markus Suta4
1Ioffe Institute, 194021, Saint Petersburg, Russia. ivanvrubel@ya.ru.
Physical chemistry chemical physics : PCCP
|July 4, 2023
概括
本研究介绍了一种基于量子的电子捕获和释放分析模型,改进了材料缺陷分析. 新模型提供了对参数的物理解释,使材料研究更加系统.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 量子力学就是量子力学.
背景情况:
- 点缺陷严重影响光学设备的性能.
- 热发光是研究缺陷诱导的电荷捕获和重组的关键.
- 现有的半经典模型缺乏量子力学的严谨性,限制了材料的推断.
研究的目的:
- 开发一种可靠的分析模型,用于从导电带 (CB) 捕获和释放非辐射电子.
- 纳入诸如斯-爱因斯坦统计和费米金律之类的量子原理.
- 提供捕获系数和频率因子的物理可解释模型,包括陷电荷状态.
主要方法:
- 由波斯-爱因斯坦统计统计为语音占用.
- 使用费米的黄金法则来进行共振电荷转移.
- 分析陷状态和导电带之间的电子捕获/释放动态.
主要成果:
- 该模型在物理上解释捕获系数和频率因子,将它们与波函数重叠和键离子性/共价性联系起来.
- 证明捕获截面不一定取决于陷深度.
- 显示与实验数据的良好一致,验证模型的预测.
结论:
- 拟议的量子模型提供了更准确的电子捕获和释放过程的描述.
- 通过提供有关陷状态的可靠信息,使系统的材料研究成为可能.
- 克服了半经典模型在材料间推断方面的局限性.
相关概念视频
Continuous Charge Distributions
6.9K
Imagine a bucket of water. It contains many molecules, of the order of 1026 molecules. Thus, although it contains discrete elements (molecules) at the microscopic level, macroscopically, it can be considered continuous. Small volume elements of water, infinitesimal compared to the bulk of the bucket's volume, still contain many molecules. Under this framework, quantized matter is approximated as continuous for practical purposes.
The electric charge can also be subjected to an analogical...
The electric charge can also be subjected to an analogical...
6.9K
Mass Analyzers: Common Types
656
The quadrupole mass analyzer consists of four cylindrical metal rods arranged in a diamond carrying a DC voltage and a radio-frequency AC voltage. The motion of ions through the quadrupole depends on the field strength, causing only ions of a certain m/z to resonate successfully and strike the detector at a given field strength. Though the transmission rate for these analyzers is high, the exact elemental composition of the sample is not determined because of low resolution; however, they are...
656
The Quantum-Mechanical Model of an Atom
42.5K
Shortly after de Broglie published his ideas that the electron in a hydrogen atom could be better thought of as being a circular standing wave instead of a particle moving in quantized circular orbits, Erwin Schrödinger extended de Broglie’s work by deriving what is now known as the Schrödinger equation. When Schrödinger applied his equation to hydrogen-like atoms, he was able to reproduce Bohr’s expression for the energy and, thus, the Rydberg formula governing hydrogen spectra.
42.5K
Coulomb's Law and The Principle of Superposition
9.1K
Coulomb's Law describes the force experienced by two point charges under each other's presence. But what if there are more than two charges? For example, if there is a third charge, does it experience a force that is a simple combination of the individual forces due to the first two charges? Can it be described mathematically?
The Principle of Superposition answers the question. Yes, Coulomb's Law applies to each pair of charges, and the net force on each charge is the vector sum of...
The Principle of Superposition answers the question. Yes, Coulomb's Law applies to each pair of charges, and the net force on each charge is the vector sum of...
9.1K
Electric Field
10.8K
Consider two point charges, each exerting Coulomb force on the other. It is possible to describe the Coulomb interaction via an intermediate step by defining a new physical quantity called the electric field.
In the new picture, imagine that the first charge sets up an electric field independent of all other charges in the universe. When another charge comes in its vicinity, the second charge experiences an electric force depending on the electric field at that point. The source charge does not...
In the new picture, imagine that the first charge sets up an electric field independent of all other charges in the universe. When another charge comes in its vicinity, the second charge experiences an electric force depending on the electric field at that point. The source charge does not...
10.8K
Energy Associated With a Charge Distribution
1.6K
The work done to bring a charge through a distance r is given by the potential difference between the initial and the final position. To assemble a collection of point charges, the total work done can be expressed in terms of the product of each pair of charges divided by their separation distance, defined with respect to a suitable origin. Solving this expression gives the energy stored in a point charge distribution.
1.6K


