无且可扩展的基于GeTe的热电模块,效率为12
Li Xie1,2, Chen Ming1, Qingfeng Song1
1State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China.
Science advances
|July 5, 2023
概括
研究人员开发了新的扩散屏障材料 (DBMs),用于无GeTe的热电设备. 这一创新提高了废热回收应用的效率和可靠性.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 能源转换 能源转换
背景情况:
- 基于GeTe的材料显示出由于其优越的热电特性,对废热回收有很大的希望.
- 热电器件的效率和可靠性受到缺乏合适的扩散屏障材料 (DBM) 的阻碍.
研究的目的:
- 为了确定基于GeTe的热电设备的有效扩散屏障材料.
- 提高热电发电机的能量转换效率和服务可靠性.
- 推进废热回收的无热电技术.
主要方法:
- 利用第一原理计算和相位平衡图来设计和识别DBM.
- 合成并通过实验验证了germanides和Ge.Te.之间的接口的化学和机械稳定性.
- 开发了一个可扩展的GeTe生产流程和优化模块几何.
主要成果:
- 确定过渡金属化物 (NiGe,FeGe2) 作为有效的DBMs.
- 确认了germanides和GeTe之间的优异界面稳定性.
- 在使用量产GeTe和Yb$_{0.3}$Co$_{4}$Sb$_{12}$的八对模块中实现了创纪录的12%的效率.
结论:
- 开发的DBM和可扩展的GeTe生产使高效,可靠,无热电器设备成为可能.
- 这一突破使使用先进的热电技术促进了废热回收的实际应用.
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