通过装有表面活性剂的水蒸气接口运输赫普坦分子
Seokgyun Ham1, Xin Wang1, Arun Kumar Narayanan Nair2
1Department of Mechanical Engineering, Virginia Tech, Blacksburg, Virginia 24061, United States.
The journal of physical chemistry. B
|July 6, 2023
概括
跨界面的分子运输是灭火的关键. 这项研究表明,表面活性剂单层显著阻碍了赫运输,抗性随表面活性剂密度的增加而增加.
科学领域:
- 物理化学 物理化学
- 表面科学是一门学科.
- 计算化学的计算化学
背景情况:
- 通过液体-蒸汽接口进行分子运输对于灭火等应用至关重要.
- 理解表面活性剂对界面传输的影响是不完整的.
研究的目的:
- 为了研究通过水蒸气接口与二甲基硫酸盐 (SDS) 单层的甲基硫酸盐 (heptane) 运输.
- 量化界面传输阻力及其对SDS密度的依赖.
主要方法:
- 使用了分子动力学模拟.
- 平均力 (PMF) 的计算潜力和heptane的局部扩散性概况.
- 分析了heptane的微环境和SDS单层的扰动.
主要成果:
- 赫普坦在SDS覆盖的接口上经历了有限的运输阻力.
- 阻力是由高PMF和SDS头组区域的缓慢扩散驱动的.
- 接口电阻与SDS密度线性增加,在和时跳跃.
结论:
- 在SDS单层中,对于赫来说,会造成很大的运输障碍.
- 通过控制表面活性剂密度,可以调整界面电阻.
- 这些发现为表面活性剂的设计提供了信息,以加强灭火和控制分子运输.
相关概念视频
Entropy and Solvation
7.1K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
7.1K
Intermolecular Forces and Physical Properties
20.9K
20.9K
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility
44.6K
Intermolecular forces are attractive forces that exist between molecules. They dictate several bulk properties, such as melting points, boiling points, and solubilities (miscibilities) of substances. Molar mass, molecular shape, and polarity affect the strength of different intermolecular forces, which influence the magnitude of physical properties across a family of molecules.
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
44.6K
Solubility
17.6K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.6K
Vapor Pressure
35.1K
When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules move randomly about, they will occasionally collide with the surface of the condensed phase, and in some cases, these collisions will result in the molecules re-entering the condensed phase. The change from the gas phase to the liquid is called condensation. When the rate of condensation becomes equal to the rate of vaporization, neither the amount of the liquid nor the amount of the vapor...
35.1K
Phase Transitions: Vaporization and Condensation
17.7K
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase...
17.7K


