通过固有的湿度调节的物理化学特性优化污泥衍生生物炭的吸附性能
Jinwen Hu1, Yanwen Shen1, Nanwen Zhu1
1School of Environmental Science & Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Waste management (New York, N.Y.)
|July 6, 2023
概括
在生物炭生产过程中增加污水污泥的湿度会增强其孔隙结构和表面积. 这提高了污泥衍生生物碳吸附四环素的能力,提供了成本效益高的污泥再利用方法.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 污水污泥管理是一个全球性的挑战,再利用策略对于可持续性至关重要.
- 污泥衍生生物炭 (SDB) 对环境应用具有前景,但其性能需要优化.
- 污泥中固有的水分通常被忽视为影响SDB特性的一个因素.
研究的目的:
- 研究固有污泥湿度对污泥衍生生物炭 (SDB) 的物理化学性质的影响.
- 为了评估不同的水分含量如何影响SDB对四环素的吸附性能.
- 通过控制污泥含水量,建立一种增强SDB应用的方法.
主要方法:
- 污水污泥的水分含量控制 (0-80%) 在400,600和800°C的温度下进行热解.
- 分析了产生的SDB的物理化学特性,包括特定表面积 (SSA) 和毛孔总体积 (TPV).
- 测量了SDB对四环素的吸附能力,以评估其应用性能.
主要成果:
- 湿度在400°C促进了微孔和中孔的发展,显著增加了SSA和TPV.
- 在更高的温度 (600/800°C) 下,水分主要促进了中孔形成,尽管SSA减少,但TPV增加.
- 由40%/80%湿度的污泥制成的SDB由于改善的孔隙结构和表面功能群体而表现出增强的四环素吸附能力.
结论:
- 污泥的水分含量是一个关键因素,可以操纵以优化SDB吸附性能.
- 在热解过程中控制的水分水平可以显著提高SDB的特定表面积,孔径和吸附能力.
- 这项研究提供了一种新的,经济的污泥再利用方法,通过定制SDB性能来去除污染物.
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