在中保持水 - - 稳定的水滴,没有表面张力
N P Longmire1, S L Showalter2, D T Banuti3,4
1Department of Mechanical Engineering, The University of New Mexico, Albuquerque, NM, 87131, USA.
Nature communications
|July 6, 2023
概括
超临界流体表现出不同的液体和气体状态,在Widom线上发生伪沸. 新的研究揭示了热梯度诱导接口 (TGIIF) 可以创建稳定的滴和接口没有表面张力.
科学领域:
- 热力学是一种热力学.
- 流体动力学 流体动力学
- 材料科学 材料科学 材料科学
背景情况:
- 超临界流体传统上被认为是无结构的,但最近的发现显示了不同的液态和气态状态.
- 一个更高阶的相位过渡,伪沸,发生在这些状态之间跨越Widom线.
- 以前,在超临界混合物中观察到的界面和液滴被归因于表面张力.
研究的目的:
- 介绍和解释一种用于超临界流体界面形成的新型物理机制.
- 挑战对滴滴和相位接口的传统理解.
- 探索这种新现象在工程中的潜在应用.
主要方法:
- 基于第一原则的理论分析.
- 在超临界条件下的流体行为的计算模拟.
主要成果:
- 稳定的水滴,气泡和平面接口可以在没有表面紧张的情况下在超临界流体中形成.
- 这种现象是由热梯度诱导接口 (TGIIF) 驱动的.
- TGIIF展示了超临界流体的意想不到的行为,与气体或液体不同.
结论:
- 超临界流体表现出超出传统表面张力模型的复杂界面现象.
- TGIIF为超临界系统中的相位行为和接口形成提供了新的视角.
- 这一发现在优化高压系统中的燃料注入和热传输方面具有潜在的应用.
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