三功能的伊米达化:一种高效的氧化还原媒介,用于高性能-O电池
Lei Wang1, Wei Li1, Xinyi Sun1
1Center of Energy Storage Materials & Technology, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, National Laboratory of Solid State Microstructures and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, P. R. China. pinghe@nju.edu.cn.
概括
这项研究介绍了用于氧电池的1-aminopropyl-3-methylimidazolium化物 (APMImBr). APMImBr通过调解Li2O2分解和保护阳极来提高性能,延长电池寿命.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 氧 (Li-O2) 电池提供高能量密度,但在循环和效率方面面临挑战.
- 过氧化物 (Li2O2) 的分解和保护金属阳极对于Li-O2电池的性能至关重要.
研究的目的:
- 为了研究1-aminopropyl-3-methylimidazolium化物 (APMImBr) 作为二甲基硫氧化基Li-O2电池中的添加剂的有效性.
- 阐明离子 (Br-) 和1-aminopropyl-3-methylimidazolium (APMIm+) 在提高电池性能方面的作用.
主要方法:
- 用APMImBr添加剂对Li-O2电池进行电化学测试.
- 对反应机制的分析,包括氧化还原调解和激素清理.
- 在金属阳极上的固体电解质介相 (SEI) 层的表征.
主要成果:
- APMImBr 作为氧化还原媒介,催化了 Li2O2 的分解.
- APMIm+吸收超氧化基,并在阳极上形成一个富含Li3N的保护性SEI层.
- 带有APMImBr的2电池表现出更大的放电容量和降低了约0.61V的充电超电位.
结论:
- APMImBr显著提高了-O2电池的性能.
- 作为调解剂和保护剂的APMImBr的双重功能导致延长周期寿命超过200个周期.
相关概念视频
Electrolysis
26.8K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.8K
Balancing Redox Equations
52.6K
Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
52.6K
Ladder Diagrams: Redox Equilibria
483
Ladder diagrams are useful tools for understanding redox equilibrium reactions, especially the effects of concentration changes on the electrochemical potential of the reaction. The vertical axis in the redox ladder diagrams represents the electrochemical potential, E. The area of predominance is demarcated using the Nernst equation.
Consider the Fe3+/Fe2+ half-reaction, which has a standard-state potential of +0.771 V. At potentials more positive than +0.771 V, Fe3+ predominates, whereas Fe2+...
Consider the Fe3+/Fe2+ half-reaction, which has a standard-state potential of +0.771 V. At potentials more positive than +0.771 V, Fe3+ predominates, whereas Fe2+...
483
Batteries and Fuel Cells
27.7K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.7K
Acid Halides to Alcohols: LiAlH4 Reduction
3.0K
Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
3.0K
Redox Equilibria: Overview
594
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
594


