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Updated: Jul 24, 2025

Constructing Thioether/Vinyl Sulfide-tethered Helical Peptides Via Photo-induced Thiol-ene/yne Hydrothiolation
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一种基于[2]rotaxane分子穿的翻译活性联体,具有2 2'-双基核的2 2'-双基核

Ayan Dhara1, Anton Dmitrienko1, Rahaf N Hussein1

  • 1Department of Chemistry and Biochemistry, University of Windsor Windsor ON N9B 3P4 Canada loeb@uwindsor.ca.

Chemical science
|July 7, 2023
PubMed
概括

这项研究合成了一个分子穿器 ([2]rotaxane) 与一个中央双基单元. 金属离子协调,特别是(II),使皇冠以太轮沿着轴进行可控的穿.

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Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.
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