高稳定性Al金属阳极通过表面化学被动启用,用于长寿命水性Al金属电池
Qingfei Hao1, Fei Chen1, Xiangtao Chen1
1Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China.
ACS applied materials & interfaces
|July 7, 2023
概括
研究人员开发了一种保护层,用于水性电池中的阳极. 这项创新提高了耐腐蚀性,并大大提高了电池的寿命,为更安全,更持久的金属电池 (AMB) 铺平了道路.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性金属电池 (AMB) 提供高能量密度,低成本和安全性.
- 由于阳极的电化学可逆性和腐蚀性差,AMB的广泛使用受到阻碍.
研究的目的:
- 制定一项战略,以提高阳极在水性电解质中的稳定性和循环性能.
- 为了解决可充电水性电池中阳极腐蚀和不均沉积的局限性.
主要方法:
- 使用快速表面被动化策略,在金属阳极上制造出由Mn/Ti/Zr化合物组成的密集被动化层.
- 处理过的阳极的性能在对称和全细胞配置中进行了评估.
主要成果:
- 这种Mn/Ti/Zr被动化层有效地促进了的均沉积,并增强了耐腐蚀性.
- 经过处理的Al阳极的对称细胞在0.1 mA cm-2.2时显示出超过300个周期的稳定循环.
- 一个全细胞原型实现了600个循环的寿命,这表明循环稳定性得到了显著改善.
结论:
- 开发的被动化层提供了一种多功能解决方案,以克服水性电池中阳极的有限循环寿命.
- 这种方法提高了高性能和安全的水性金属电池的实际适用性.
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