氧气吸收对碳纤维的影响
Timothy M Harrell1, Alexander Scherschel1, Cole Love-Baker1
1Department of Mechanical and Aerospace Engineering, University of Virginia, 122 Engineer's Way, Charlottesville, VA, 22904, USA.
Small (Weinheim an der Bergstrasse, Germany)
|July 7, 2023
概括
使用氧化对中相杆纤维的热稳定对于碳纤维的完整性至关重要. 这项研究优化了氧化条件 (温度,体重增加) 以提高最终碳纤维的机械性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 复合材料 复合材料 复合材料
背景情况:
- 碳纤维生产需要热稳定前体,如多烯和.
- 稳定防止了碳化过程中的分解,确保了结构完整性.
- 半相位稳定通常涉及引入含氧功能组.
研究的目的:
- 为了研究不同氧化温度和重量百分比上升对中相位前体纤维的影响.
- 分析稳定条件与产生的碳纤维的微观结构和机械性能之间的关系.
主要方法:
- 现场差异扫描热度计 (DSC) 和热重度计分析 (TGA) 用于研究氧化过程.
- 在260,280和290°C的温度下氧化了mesophase基前体纤维,重量增加了1,3.5,5和7.5%的重量.
- 氧化纤维随后被碳化,并测试了拉伸力学性能.
主要成果:
- 该研究确定了最佳的温度和重量百分比增加,以有效地热稳定中相杆纤维.
- 分析揭示了不同的稳定条件如何影响纤维微观结构.
- 机械测试证明了稳定对最终碳纤维的拉伸性能的影响.
结论:
- 优化的热稳定对于从中位相中获得的碳纤维中实现所需的机械性能至关重要.
- 了解稳定参数,微观结构和机械性能之间的相互作用是先进碳纤维开发的关键.
- 这项研究为通过受控前体稳定定定碳纤维特性提供了宝贵的见解.
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