在-10°C时打开硫充满电池
Hun Kim1, Jang-Yeon Hwang1,2, Young-Geun Ham1
1Department of Energy Engineering, Hanyang University, Seoul 04763, South Korea.
ACS nano
|July 10, 2023
概括
酸使硫 (Li-S) 电池能够在零度以下的温度下工作. 这种添加剂提高了Li-S的利用率,提高了在寒冷条件下的性能和稳定性.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硫 (Li-S) 电池提供高能量密度和安全性.
- 当前的Li-S电池在零度以下的温度下难以利用Li2S的低电化学利用.
- 开发可冷操作的Li-S电池对于更广泛的应用至关重要.
研究的目的:
- 为了使 Li-S 充满电池与 Li2S 阴极和 Li-free 阳极在零度以下的温度下有效运行.
- 调查添加剂在提高Li-S电池低温性能方面的作用.
- 为了提高Li2S在-10°C的电化学利用.
主要方法:
- 引入酸 (NH4NO3) 作为Li-S全电池中的功能添加剂.
- 分析NH4NO3.3诱导的Li2S改变的激活路径.
- 研究Li2S表面无形化及其对转化反应的影响.
主要成果:
- NH4NO3促进了Li-S充满电池在-10°C的运行.
- 添加剂诱导Li2S表面溶解和无形化.
- 通过不成比例和直接转化反应,有效地将Li2S转化为S8.
- 达到可逆容量和400多个周期的循环稳定性在-10°C.
结论:
- 酸是低温Li-S电池运行的一个有前途的添加剂.
- 添加剂的极性N-H键修改了Li2S激活,改善了电化学利用.
- 在寒冷的环境中证明了高性能Li-S电池的可行途径.
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