在金属有机框架内被困的2-cyclopenten-1-one的灾难选择性客体形状依赖的 [2+2] - 光极化

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Updated: Jul 23, 2025

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

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Pavel A Demakov1, Danil N Dybtsev1, Vladimir P Fedin1

  • 1Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Akad. Lavrentieva Ave., Novosibirsk 630090, Russia. demakov@niic.nsc.ru.

Chemical communications (Cambridge, England)
|July 11, 2023
PubMed
概括

这项研究表明,在金属有机框架内,紫外线诱导的 [2+2] 乙二元化. 晶体结构促进了简单且分立选择性反应,产生了特定的抗二极体.

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