从合成无氧发酵超中通过维亚尼特结晶恢复:各种物理化学过程参数的合效应
Jia-Shun Cao1, Su-Na Wang1, Run-Ze Xu1
1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China.
The Science of the total environment
|July 11, 2023
概括
使用维亚尼特结晶从废水中恢复是高效的. 优化pH,Fe/P和速度可以提高回收率,并影响晶体特性,从而更好地回收资源.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 维维亚尼特结晶提供了一种有效的 (P) 从无氧发酵超的回收方法.
- 超浮物中的多糖和蛋白质等有机成分可以影响维亚尼特晶体的特性.
研究的目的:
- 为了研究不同超浮成分对维亚尼特结晶的影响.
- 通过vivianite结晶来优化P回收的反应参数.
- 使用热力学建模,将维维亚尼特晶体特性与超和相关联.
主要方法:
- 探索成分对维亚尼特结晶的作用.
- 响应表面的方法来优化pH,Fe/P比和速度.
- 热力学平衡建模以分析晶体特性和超和.
主要成果:
- 优化参数 (pH 7.8,Fe/P 1.74,500rpm) 实现了90.54%的P回收.
- 反应参数影响了维维亚尼特的形态,大小和纯度,而不是晶体结构.
- 增加pH值和Fe/P比率提高了和指数 (SI),促进了结晶.
- 高SI (>11) 导致同质核化,导致较小的晶体大小.
结论:
- 优化vivianite结晶是一种高效的过程,用于从废水中回收.
- 了解超和和核的关系是控制晶体大小和纯度的关键.
- 这些发现支持vivianite结晶的大规模应用,用于废水处理和资源回收.
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