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相关概念视频

Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

10.6K
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
10.6K
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate02:21

Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate

11.9K
Alkenes can be dihydroxylated using potassium permanganate.  The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.
11.9K
Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids02:04

Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids

5.9K
Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti dihydroxylation. The process involves treating an alkene with a peroxycarboxylic acid to form an epoxide. Epoxides are highly strained three-membered rings with oxygen and two carbons occupying the corners of an equilateral triangle. This step is followed by ring-opening of the epoxide in the presence of an aqueous acid to give a trans diol.
5.9K
Oxidation of Alcohols02:37

Oxidation of Alcohols

13.3K
In this lesson, the oxidation of alcohols is discussed in depth. The various reagents used for oxidation of primary and secondary alcohols are detailed, and their mechanism of action is provided.
The process of oxidation in a chemical reaction is observed in any of the three forms:
13.3K
Acid-Catalyzed Ring-Opening of Epoxides02:24

Acid-Catalyzed Ring-Opening of Epoxides

7.4K
Epoxides that are three-membered ring systems are more reactive than other cyclic and acyclic ethers. The high reactivity of epoxides originates from the strain present in the ring. This ring strain acts as a driving force for epoxides to undergo ring-opening reactions either with halogen acids or weak nucleophiles in the presence of mild acid. The acid catalyst converts the epoxide oxygen, a poor leaving group, into an oxonium ion, a better leaving group, making the reaction feasible. The...
7.4K
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide02:44

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

10.4K
Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
10.4K

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相关实验视频

Updated: Jul 23, 2025

Protocol of Electrochemical Test and Characterization of Aprotic Li-O2 Battery
08:18

Protocol of Electrochemical Test and Characterization of Aprotic Li-O2 Battery

Published on: July 12, 2016

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增强酸氧进化活动的旋转偏振策略.

Ling Li1, Jing Zhou2, Xiao Wang3

  • 1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Jiangsu, 215123, China.

Advanced materials (Deerfield Beach, Fla.)
|July 12, 2023
PubMed
概括

这项研究引入了一种新的旋转极化策略,使用添加的二氧化 (RuO2) 来促进酸氧演化反应 (OER),用于工业应用.

关键词:
二氧化 (RuO2) 是一种有机物.酸性酸是指一种酸性酸.磁场的磁场是磁场的磁场.氧气进化反应反应 氧气进化反应旋转 旋转 旋转 旋转

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Detection of Nitric Oxide and Superoxide Radical Anion by Electron Paramagnetic Resonance Spectroscopy from Cells using Spin Traps
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Detection of Nitric Oxide and Superoxide Radical Anion by Electron Paramagnetic Resonance Spectroscopy from Cells using Spin Traps

Published on: August 18, 2012

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Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
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Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance

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相关实验视频

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Protocol of Electrochemical Test and Characterization of Aprotic Li-O2 Battery
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Protocol of Electrochemical Test and Characterization of Aprotic Li-O2 Battery

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Detection of Nitric Oxide and Superoxide Radical Anion by Electron Paramagnetic Resonance Spectroscopy from Cells using Spin Traps
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Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 催化剂是一种催化剂.

背景情况:

  • 旋转极化是一种有前途的方法,可以增强氧进化反应 (OER),因为中间体和产品的旋转依赖行为.
  • 对于酸性OER,实际上已经报告了很少的铁磁催化剂,限制了工业应用.

研究的目的:

  • 开发一种旋转偏振媒介的策略,在抗铁磁RuO2.2中产生铁磁.
  • 通过稀释 (Mn2+) 兴奋剂来增强RuO2的酸性OER活性.

主要方法:

  • 稀释Mn2+对RuO2进行化以诱导铁磁.
  • 要素选择性X射线磁性圆形二元化 (XMCD) 来探测磁性合.
  • 解释磁相互作用的第一原则计算.
  • 电化学测量以评估OER活动和稳定性.

主要成果:

  • 证实了和离子之间的铁磁合,符合古登诺-卡纳莫里规则.
  • -化RuO2 (Mn-RuO2) 呈现出增强的OER活性,在10 mA cm-2.2时具有143 mV的低超电位.
  • 磁场显著增强了OER活动和稳定性,在480小时内呈现微不足道的衰变.
  • 内在转速频率在1.45 VRHE时提高到5.5 s-1.

结论:

  • 开发的旋转工程战略有效地增强了酸性OER活动和RuO2.2的稳定性.
  • 这项工作通过利用自旋特性来设计高效的电催化剂的新途径.