用酸和聚乙烯胺改性零价值铁颗粒选择性去除Cr(VI),具有空气稳定性
Meng Wang1, Yingbo Chen1, Yuanyuan Zhang1
1School of Materials Science and Engineering, State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin 300387, PR China.
Journal of hazardous materials
|July 13, 2023
概括
一种新的复合吸附剂Fe-TA-PEI-10通过吸附和减少有效地从废水中去除有毒的Cr (VI). 这种稳定且可再生的材料为高效重金属整治提供了有前途的解决方案.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 水处理 处理水的方法
背景情况:
- 六价 (Cr(VI)) 是工业废水中高度有毒的污染物.
- 现有的Cr6去除方法经常面临效率,稳定性和再生方面的挑战.
研究的目的:
- 开发一种新的,稳定的,可再生的复合吸附剂,以有效地去除CrVI.
- 通过开发的吸附剂来研究Cr (VI) 去除的机制.
主要方法:
- 将聚乙烯胺 (PEI) 固定在由酸 (TA) 稳定的零价值铁 (ZVI) 颗粒上.
- 使用电化学分析对吸附剂 (Fe-TA-PEI-10) 的表征.
- 吸附研究以确定吸附动力学和异温物.
- 在暴露于环境空气下的稳定性测试.
主要成果:
- Fe-TA-PEI-10在通过吸附和降解到Cr (III) 的方式去除Cr (VI) 方面表现出高效率.
- 吸附剂在空气中保持了30天的良好稳定性,没有性能损失.
- 吸附遵循伪第一阶动力学和兰木尔异热模型,最大容量为161.6 mg/g.
- 该材料在模拟电废水中显示出对Cr(VI) 的高选择性.
结论:
- Fe-TA-PEI-10是一种有效,稳定和可再生的吸附剂,用于去除CrVI.
- TA和PEI的组合通过改进的电子传输和静电相互作用来提高吸附剂的性能.
- 这项研究提出了一种新的方法,用于开发用于重金属修复的长时间活性吸附剂.
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