低温处理波赫米特石使用贝耶尔还原方法,形成高铁磁铁矿度
Andrei Shoppert1,2, Dmitry Valeev3, Irina Loginova1
1Department of Non-Ferrous Metals Metallurgy, Ural Federal University, 620002 Yekaterinburg, Russia.
Materials (Basel, Switzerland)
|July 14, 2023
概括
这项研究探讨了用于石加工的大气压洗,旨在减少废物并改善生产. 研究人员研究了将铁矿物转化为磁铁的方法,提高了效率.
科学领域:
- 金工程 金工程 金工程
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
背景情况:
- 拜耳工艺在生产中占主导地位,产生大量的矿残留物 (BR) 废物,特别是来自低质量的矿.
- 现有的贝耶尔减少方法用于消除BR,需要在220°C以上的高压洗.
- 开发高效的低温方法来加工石和减少废物至关重要.
研究的目的:
- 为了研究波赫米特石在大气压下脱水的情况.
- 为了评估在漏过程中血同时降解为磁.
- 评估第一阶段和第二阶段大气压洗或第二阶段高压洗的可行性.
主要方法:
- 使用XRD,SEM-EDS和Mössbauer光谱对石和NaOH水残留物的表征.
- 在大气压下用Fe (II) 添加强溶液 (330-400克L-1Na2O) 进行洗.
- 随后使用拜耳工艺母液进行大气 (120°C) 或高压 (160-220°C) 浸出.
主要成果:
- 大气压液提取>60%Si和5-25%Al在1小时内,与部分铁矿物减少.
- 在第二个浸出阶段后,获得了含有> 83% 质量的磁铁的缩物.
- 大气压浸出用于脱和降铁的已证明可行性.
结论:
- 大气压水是一种可行的替代方法,用于加工波赫米特石,减少能源需求.
- 开发的方法有助于铁矿物转化为磁铁,可能有助于石残留物管理.
- 这项研究为更可持续的生产和废物利用提供了有希望的途径.
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