在中子和质子辐射下,D9奥氏体钢中的纳米集群演变
Suraj Venkateshwaran Mullurkara1,2,3, Akshara Bejawada1,2, Amrita Sen1,4
1School of Materials Engineering, Purdue University, West Lafayette, IN 47907, USA.
Materials (Basel, Switzerland)
|July 14, 2023
概括
奥氏体不钢D9显示了中子辐射后的Ni-Si纳米集群,而不是质子. 这些星团具有Ni核心-Si外结构,为先进的核反应堆提供了对其核形成和生长机制的见解.
科学领域:
- 材料科学 材料科学 材料科学
- 核工程 核工程是指核工程.
- 物理金学 物理金学
背景情况:
- 奥氏体不钢D9是第四代核反应堆结构材料的候选材料.
- 与300系列钢相比,D9具有增强的辐射耐受性和高温爬行强度.
- 在D9中辐射诱导的Ni-Si聚合的机制尚不清楚.
研究的目的:
- 描述D9.9中Ni-Si纳米团的化学和形态.
- 研究中子和质子辐射对纳米团形成的影响.
- 阐明这些纳米集群的核和生长机制.
主要方法:
- 原子探头断层扫描 (APT) 用于化学和形态特征.
- 样品经过中子或质子辐射.
- 辐射条件包括每原子5-9位移 (dpa) 的剂量和430-683°C的温度.
主要成果:
- 纳米集群仅在中子辐射后形成,而不是质子辐射.
- 纳米集群形成呈现出经典的粗化,随着剂量和温度的增加.
- 纳米集群显示了一个Ni核心-Si外结构,具有Ni3Si静态度.
结论:
- 芯-Si外结构表明一种独特的核化机制,涉及类似于旋转的波动.
- 随后的增长很可能是由的快速扩散驱动的.
- APT对于理解奥氏体不钢中不寻常的辐射诱导的纳米集群核形成至关重要.
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