酸基材料作为离子和离子电池中的阳极:一篇评论
You-Kang Duan1,2,3, Zhi-Wei Li1,2,3, Shi-Chun Zhang1,2,3
1Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China.
Molecules (Basel, Switzerland)
|July 14, 2023
概括
二元金属氧化物酸对下一代电池具有前景. 探索纳米化和兴奋剂等策略,以克服这些先进的阳极材料中的容量衰减问题.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 二元金属氧化物酸盐 (M2SnO4) 是离子电池 (LIB) 和离子电池 (SIB) 的有前途的阳极材料,因为它具有高的理论容量和合适的操作电压.
- 然而,由于在离子插入/提取过程中体积显著膨胀而导致的容量恶化,它们的实际应用受到阻碍.
研究的目的:
- 分析基于M2SnO4的阳极材料的优点和挑战.
- 讨论减轻容量衰减和提高这些材料对下一代电池的性能的策略.
主要方法:
- 对M2SnO4阳极材料的现有研究进行审查和分析.
- 讨论各种策略,包括纳米化,结构设计,兴奋剂,MOF衍生和异构构造.
主要成果:
- M2SnO4材料具有优良的电化学性能,但由于体积膨胀,其循环稳定性较差.
- 已经研究了几种策略来解决这些稳定性问题并提高绩效.
结论:
- 优化M2SnO4阳极材料需要通过创新的材料设计和合成方法解决体积扩张的挑战.
- 对这些策略的进一步研究将促进M2SnO4在先进的能量存储设备中的理论理解和实际应用.
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