生态友好型环氧终结聚氨改性环氧树脂,有效提高性
Kun Zhang1, Jinrui Huang1, Yigang Wang1
1Key Laboratory of Biomass Energy and Material, Jiangsu Province, Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Key Laboratory of Chemical Engineering of Forest Products, National Forestry and Grassland Administration, National Engineering Research Center for Low-Carbon Processing and Utilization of Forest Biomass, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China.
Polymers
|July 14, 2023
概括
这项研究引入了一种环保方法,使用环氧终结聚氨 (EPU) 增强环氧树脂. 在不损害热性质的情况下,EPU显著提高了性和破裂时的延长,性能优于异酸盐终结聚氨.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 复合材料 复合材料 复合材料
背景情况:
- 聚氨是环氧树脂的常见硬化剂.
- 使用异酸盐终结聚氨 (ITPU) 的现有方法存在缺点,包括严格的存储,有限的兼容性和溶剂使用.
- 这些局限性阻碍了硬化环氧树脂的更广泛应用.
研究的目的:
- 开发一种简单,绿色的方法来制备硬化环氧树脂.
- 调查环氧终结聚氨 (EPU) 作为硬化剂的有效性.
- 为了比较EPU与传统ITPU的性能.
主要方法:
- 使用一种新的无溶剂方法来合成EPU修饰的环氧树脂.
- 不同度的EPU被纳入了环氧树脂矩阵.
- 评估了机械性能 (硬度,破裂时的延长) 和热性能 (玻璃过渡温度,热稳定性).
主要成果:
- 添加EPU显著提高了环氧树脂的性和破裂时的延长.
- 30重%的EPU含量导致358.36%的破裂延伸增加和73.56%的性增加.
- 与ITPU相比,EPU表现出优越的硬化性能,对玻璃过渡温度和热稳定性的影响最小.
结论:
- 环氧终结聚氨为固环氧树脂提供了一个有希望的,绿色的替代品.
- 开发的方法克服了与ITPU相关的局限性.
- 修改EPU可以显著提高机械性能,而不会对热性能产生重大影响.
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